I have been using WLM for a few months. 

1-I just changed my URL and added the eamil to WLM through Go Daddy, but sent mail is going into the Storage box and I have to manually send it.

2-I am also getting a POP up through WLM:

Delete the photo email, create a new one, and try to send it again.

Server: 'smtp.office365.com'
Windows Live Mail Error ID: 0x8CCC0003
Protocol: SMTP
Port: 587
Secure(SSL): Yes

3-I am trying to make DeborahShane.com email my default and I highlight that email but it is not setting it?

Help and thanks