I have a similar problem that I hope somebody can help.
I have Windows Live Mail operating on Windows 8 because Comcast must use PoP3 and Windows 8 does not support PoP3.
I can receive email via Comcast using Live Mail.
I cannot send email via Comcast using Live Mail. This is the problem.
I can send email using the Comcast web email interface and other computers in our home can receive and send email via Comcast using Outlook. so apparently it is not a Comcast problem.
I receive the following error message when I try to send a message:
The connection to the server has failed
Subject: TEST MESSAGE (the message I tried to send)
Server 'smtp.comcast.net'
Windows Live Error ID 0x00CCC0E
Protocol SMTP
Port 25
Secure (SSL) No
Socket Error 10013
Split from a similar but unrelated thread 
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