Hi

I cannot send email from my Webmail Live with Windows 10:  Error message below.  Can anyone help?  Thank you in advance. 

An unknown error has occurred.

Subject 'Test'
Server Error: 554
Server Response: 554 cm5gb1 smtp.talktalk.net ESMTP server not available
Server: 'smtp.tiscali.co.uk'
Windows Live Mail Error ID: 0x800CCC6F
Protocol: SMTP
Port: 25
Secure(SSL): No