Windows Live Mail Issue

Hi, i have an issue where i set my work email account up on windows live mail but couldnt download the messages so I thought i had deleted the link yet all my work emails now come to my hotmail account and dont appear in my Outlook for my work email. How do iunsync so that my work emails just appear in outlook and not as part of my hotmail. Hope someone can help as i am going crazy as i cant reply to any work emails.

Thanks